Butler-Volmer Electrochemical Kinetics L1-311

Computational ChemistryElectrode charge-transfer kineticsδ=3 · standardL_DAG = 2.8📋 Stub — not mineable

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Unclaimed Principle — open for contribution

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Forward model E

i = i_{0} \cdot (e x p (a l p h a_{a} \cdot F \cdot e t a / R T) - e x p (- a l p h a_{c} \cdot F \cdot e t a / R T))

Butler-Volmer current-overpotential: i = i_0 * (exp(alpha_a*F*eta/RT) - exp(-alpha_c*F*eta/RT)); describes electron-transfer rate at electrode.

L-DAG

E.butler_volmer -> E.mass_transport -> O.i_eta

E.butler_volmerE.mass_transportO.i_eta

Well-posedness W

Existence:: true
Uniqueness:: true
Stability:: conditional
κ:: 80

Well-posed; inversion clean in Tafel regime.

Solvability C

Solver class:: Nonlinear LM; Bayesian inference for BV parameters
Convergence rate q:: 2
Complexity:: principle-dependent

Specs (0)

No L2 specs registered yet for this principle.