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STEM-EDX — X-ray energy-dispersive elemental mapping L1-094

Electron MicroscopyChemical composition via characteristic X-raysδ=3 · standardL_DAG = 3.4📋 Stub — not mineable
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Unclaimed Principle — open for contribution

This Principle is declared in the catalog but has no reference solver, no pinned dataset, and is not registered on-chain. There is no reward pool. Submitting a cert against this Principle today will record the cert for reproducibility but pay zero PWM.

To claim it as a Bounty #7 contribution: open a PR adding (1) a reference solver, (2) ≥1 dataset pinned to IPFS, (3) updates to the L3 manifest with dataset CIDs. After verifier-agent triple-review, the founders' 3-of-5 multisig signs PWMRegistry.register() and the Principle becomes mineable.

Forward model E

STEM-EDX — X-ray energy-dispersive elemental mapping: edx characteristic xray produces the measurement through a 4-node primitive DAG L.illumination.convergent_probe -> S.scan.raster -> D.edx_detector -> int.spectral, with spectral-channel integration and photon-shot-noise-limited (Poisson counting). Recovery is posed as a linear inverse problem that inverts the forward operator to estimate the scene-side elemental concentration map. Difficulty tier delta=3 with effective condition number kappa_eff~10; calibration-level mismatch (detector_dead_time, peak_overlap, absorption_correction) sets the accuracy floor at the Omega boundary. See the forward_model field for the closed-form imaging equation.

L-DAG

L.illumination.convergent_probe -> S.scan.raster -> D.edx_detector -> int.spectral
L.illumination.convergent_probeS.scan.rasterD.edx_detectorint.spectral

Well-posedness W

Existence:
true
Uniqueness:
true
Stability:
conditional
κ:
200

Existence of the recovered elemental concentration map is guaranteed within the declared Omega bounds. Uniqueness holds on the measurement-supported subspace; out-of-support modes are controlled by the declared priors. Stability is moderately conditioned (kappa_eff ~= 10); detector_dead_time dominates the stability cliff; peak_overlap and the remaining mismatch parameters contribute higher-order bias terms. Photon-shot-noise-limited (poisson counting) sets the irreducible data-fidelity floor, while mild Tikhonov or analytic inversion is sufficient at the nominal Omega point.

Solvability C

Solver class:
linear-operator + convex optimisation [Background-subtract, NMF-EDX] | linear-operator + deep neural prior [EDX-Net]
Convergence rate q:
2
Complexity:
O(H * W * log(...)) per iteration; learned variants: O(H W Z * F_theta_cost) per forward pass

Specs (0)

No L2 specs registered yet for this principle.